The role of [η2-bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt(I) as an intermediate in the alkyne dimerisation

Dicarbonyl(η5-cyclopentadienyl)cobalt(I) (1) reacts with the electron-poor alkyne bis(tert-butylsulfonyl)acetylene to give the corresponding cyclobutadiene complex 6, whereas the reaction of [CpCo(CO)2] with dimethyl acetylenedicarboxylate yields the cyclopentadienone complex 7 under the same condit...

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Bibliographic Details

Main Authors:	Stäb, Tobias (Author) , Chávez, Jorge A. (Author) , Gleiter, Rolf (Author) , Nuber, Bernhard (Author)
Format:	Article (Journal) Festschrift
Language:	English
Published:	September 8, 2005
In:	European journal of inorganic chemistry Year: 2005, Issue: 20, Pages: 4090-4093
ISSN:	1099-0682
DOI:	10.1002/ejic.200500394
Subjects:	Festschrift
Online Access:	Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.200500394 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200500394
Author Notes:	Tobias H. Staeb, Jorge Chávez, Rolf Gleiter, and Bernhard Nuber