The role of [η2-bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt(I) as an intermediate in the alkyne dimerisation
Dicarbonyl(η5-cyclopentadienyl)cobalt(I) (1) reacts with the electron-poor alkyne bis(tert-butylsulfonyl)acetylene to give the corresponding cyclobutadiene complex 6, whereas the reaction of [CpCo(CO)2] with dimethyl acetylenedicarboxylate yields the cyclopentadienone complex 7 under the same condit...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
September 8, 2005
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| In: |
European journal of inorganic chemistry
Year: 2005, Heft: 20, Pages: 4090-4093 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.200500394 |
| Schlagworte: | |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.200500394 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200500394 |
| Verfasserangaben: | Tobias H. Staeb, Jorge Chávez, Rolf Gleiter, and Bernhard Nuber |
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Reactivity of the [η2-bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt complex towards electron-rich and -poor ccetylenes
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