1,8-Diazabicyclo[6.6.6]eicosa-4,11,17-triyne: a flexible cage for protons, copper(I) and silver(I)
X-Ray structure analysis of the diprotonated cage of 3 and its silver(I) and copper(I) complexes reveals in all three cases the in,in conformation and a significant shortening of the intrabridgehead distance from 5.05 Å in 3 to 4.85 Å for 3·2H+, 4.23 Å for 3·Cu+ and 4.61 Å for 3·Ag+.
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
1999
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| In: |
Chemical communications
Year: 1999, Issue: 2, Pages: 171-172 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/A808068B |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/A808068B Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/1999/cc/a808068b 
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| Author Notes: | Andreas Kunze, Rolf Gleiter and Frank Rominger |
| Summary: | X-Ray structure analysis of the diprotonated cage of 3 and its silver(I) and copper(I) complexes reveals in all three cases the in,in conformation and a significant shortening of the intrabridgehead distance from 5.05 Å in 3 to 4.85 Å for 3·2H+, 4.23 Å for 3·Cu+ and 4.61 Å for 3·Ag+. |
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| Item Description: | Gesehen am 28.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/A808068B |