Fourfold alkoxy-substituted (2.2.2)paracyclophane-1,9,17-trienes-ROMP into PPVs with unusual topologies
The synthesis of two 4,7,12,15-tetrakisalkoxy-substituted [2.2.2]-paracyclophane-1,9,17-trienes and their polymerization employing ring opening metathesis polymerization (ROMP) using Ru-carbenes (third-generation Grubbs catalyst) is reported. Phenylene ethynylene trimers are reduced via a Grignard r...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
12 November 2014
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| In: |
Macromolecular rapid communications
Year: 2014, Volume: 35, Issue: 24, Pages: 2096-2100 |
| ISSN: | 1521-3927 |
| DOI: | 10.1002/marc.201400515 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/marc.201400515 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.201400515 
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| Author Notes: | Dominic Mäker, Uwe H.F. Bunz |
| Summary: | The synthesis of two 4,7,12,15-tetrakisalkoxy-substituted [2.2.2]-paracyclophane-1,9,17-trienes and their polymerization employing ring opening metathesis polymerization (ROMP) using Ru-carbenes (third-generation Grubbs catalyst) is reported. Phenylene ethynylene trimers are reduced via a Grignard reagent, followed by an intramolecular McMurry cyclization to give the cyclophenes. The cyclophenes are polymerized into soluble poly(para-phenylene vinylene)s (PPV), which are analyzed in solution by NMR, UV-vis, and fluorescence spectroscopy. They are spin coated into amorphous, fluorescent thin films, and investigated by optical spectroscopy and cyclic voltammetry. |
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| Item Description: | Gesehen am 28.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3927 |
| DOI: | 10.1002/marc.201400515 |