Buchumschlag

Interaction of cyclic thiadiynes with CpCo(COD): selectivity and reactivity

The reaction of CpCo(COD) with several cyclic thiadiynes leads to selective product formation; according to their ring size either (2,5)[2.2]thiophenophanes or CpCo-stabilized cyclobutadienes were formed. The outcome of the reaction can be attributed to the geometry in the transition states, 6 and 1...

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Bibliographische Detailangaben
Hauptverfasser: Gleiter, Rolf (VerfasserIn) , Claßen, Jörg (VerfasserIn) , Rausch, Bernhard J. (VerfasserIn) , Oeser, Thomas (VerfasserIn) , Rominger, Frank (VerfasserIn)
Dokumenttyp: Article (Journal) Festschrift
Sprache:Englisch
Veröffentlicht: 2002
In: Journal of organometallic chemistry
Year: 2001, Jahrgang: 641, Heft: 1-2, Pages: 3-8
ISSN:1872-8561
DOI:10.1016/S0022-328X(01)01295-5
Schlagworte:
Festschrift
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/S0022-328X(01)01295-5
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X01012955
Volltext
Verfasserangaben:Rolf Gleiter, Jörg Classen, Bernhard J Rausch, Thomas Oeser, Frank Rominger
Beschreibung
Zusammenfassung:The reaction of CpCo(COD) with several cyclic thiadiynes leads to selective product formation; according to their ring size either (2,5)[2.2]thiophenophanes or CpCo-stabilized cyclobutadienes were formed. The outcome of the reaction can be attributed to the geometry in the transition states, 6 and 11. X-ray structure analyses of the reacting thiacycles and the isolated CpCo compounds are given and correlated with the tautness of the cobaltols.
Beschreibung:Available online 14 December 2001
Dedicated to Professor Marianne Baudler on the occasion of her 80th birthday
Gesehen am 28.10.2020
Beschreibung:Online Resource
ISSN:1872-8561
DOI:10.1016/S0022-328X(01)01295-5

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