An alkynyltelluronium iodide and its solid state structure: evidence for p→σ* interactions
The synthesis of the first alkynyltelluronium salt is presented. X-ray investigations of this species reveal a two-dimensional polymeric structure, assembled through various secondary Te⋯Te and Te ⋯I interactions. The structure itself can be rationalized in terms of p→σ* interactions.
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 January 2004
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| In: |
Journal of organometallic chemistry
Year: 2004, Volume: 689, Issue: 3, Pages: 627-630 |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2003.11.016 |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2003.11.016 Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X03011768 
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| Author Notes: | Daniel B Werz, Rolf Gleiter, Frank Rominger |
| Summary: | The synthesis of the first alkynyltelluronium salt is presented. X-ray investigations of this species reveal a two-dimensional polymeric structure, assembled through various secondary Te⋯Te and Te ⋯I interactions. The structure itself can be rationalized in terms of p→σ* interactions. |
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| Item Description: | Im Titel erscheint der Stern hochgestellt Gesehen am 30.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2003.11.016 |