Cyclic thiatetraynes: syntheses and structural properties
The syntheses of three cyclic dithiatetraynes 4-6 with the sulfur atoms in propargylic positions are reported. Their structural features have been studied by means of X-ray analysis on single crystals. Additionally, six cyclic octathiatetraynes 15-20 with sulfur atoms in α,α′-positions to the triple...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2002
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| In: |
Perkin
Year: 2001, Issue: 1, Pages: 72-76 |
| ISSN: | 1364-5471 |
| DOI: | 10.1039/B108403H |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/B108403H Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2002/p2/b108403h 
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| Author Notes: | Bernhard J. Rausch, Daniel B. Werz, Stefan Rittinger, Rolf Gleiter, Thomas Oeser and Frank Rominger |
| Summary: | The syntheses of three cyclic dithiatetraynes 4-6 with the sulfur atoms in propargylic positions are reported. Their structural features have been studied by means of X-ray analysis on single crystals. Additionally, six cyclic octathiatetraynes 15-20 with sulfur atoms in α,α′-positions to the triple bond have been prepared. The structures of 15 and 17 have been elucidated by means of X-ray analysis. These macrocycles exhibit an ellipsoidal geometry dominated by the stiff triple bond moieties. In the case of 4 a three-dimensional columnar structure is found, demonstrating the unique features of the potential cavities. |
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| Item Description: | First published as an advance article on the web 27th November 2001 Gesehen am 04.11.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1364-5471 |
| DOI: | 10.1039/B108403H |