In situ generation of endohedral metallocenophanes of cobalt and rhodium with one cyclopentadienone unit
Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis.
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
07/30/2002
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| In: |
Organic letters
Year: 2002, Volume: 4, Issue: 17, Pages: 2889-2892 |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol026287h |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol026287h Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/ol026287h 
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| Author Notes: | Gerald Scholz, Carsten Schaefer, Frank Rominger, and Rolf Gleiter |
| Summary: | Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis. |
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| Item Description: | Gesehen am 06.11.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol026287h |