In situ generation of endohedral metallocenophanes of cobalt and rhodium with one cyclopentadienone unit
Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis.
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
07/30/2002
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| In: |
Organic letters
Year: 2002, Jahrgang: 4, Heft: 17, Pages: 2889-2892 |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol026287h |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol026287h Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/ol026287h |
| Verfasserangaben: | Gerald Scholz, Carsten Schaefer, Frank Rominger, and Rolf Gleiter |
| Zusammenfassung: | Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis. |
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| Beschreibung: | Gesehen am 06.11.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol026287h |