In situ generation of endohedral metallocenophanes of cobalt and rhodium with one cyclopentadienone unit

Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis.

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Bibliographische Detailangaben
Hauptverfasser: Scholz, Gerald (VerfasserIn) , Schaefer, Carsten (VerfasserIn) , Rominger, Frank (VerfasserIn) , Gleiter, Rolf (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 07/30/2002
In: Organic letters
Year: 2002, Jahrgang: 4, Heft: 17, Pages: 2889-2892
ISSN:1523-7052
DOI:10.1021/ol026287h
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol026287h
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/ol026287h
Volltext
Verfasserangaben:Gerald Scholz, Carsten Schaefer, Frank Rominger, and Rolf Gleiter
Beschreibung
Zusammenfassung:Endohedral metallocenophanes of cobalt and rhodium were prepared using thermolysis of cyclopentadienylmetaldicarbonyl complexes bearing two alkyne units. In the case of the rhodium cyclopentadienonophanes, the structures of two isomeric complexes were confirmed by X-ray diffraction analysis.
Beschreibung:Gesehen am 06.11.2020
Beschreibung:Online Resource
ISSN:1523-7052
DOI:10.1021/ol026287h