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Isolation of bis(η2-nitrato)(η4-cyclobutadiene)cobalt(II) complexes from the oxidation of sterically hindered CpCo-stabilized cyclobutadiene complexes

The oxidation of sterically hindered, CpCo-protected cyclobutadienes with ceric ammonium nitrate (CAN) yielded the paramagnetic Co(NO3)2-protected cyclobutadiene products. These half-sandwich complexes represent possible intermediates within the mechanism of the CAN decomplexation of CpCo−cyclobutad...

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Bibliographic Details
Main Authors: Schaefer, Carsten (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 04/15/2004
In: Organometallics
Year: 2004, Volume: 23, Issue: 10, Pages: 2225-2227
ISSN:1520-6041
DOI:10.1021/om049907m
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om049907m
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/abs/10.1021/om049907m
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Author Notes:Carsten Schaefer, Rolf Gleiter, and Frank Rominger
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Summary:The oxidation of sterically hindered, CpCo-protected cyclobutadienes with ceric ammonium nitrate (CAN) yielded the paramagnetic Co(NO3)2-protected cyclobutadiene products. These half-sandwich complexes represent possible intermediates within the mechanism of the CAN decomplexation of CpCo−cyclobutadiene complexes.
Item Description:Im Titel erscheinen die Ziffern 2 und 4 hochgestellt
Gesehen am 11.11.2020
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/om049907m

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