Synthesis and properties of cyclic phosphadiynes

The first synthesis of medium-sized cyclic 1-arylphosphadiynes is reported. Details of the molecular structure of 1-phenylphosphacyclododeca-3,10-diyne sulfide (9b) and 1-(2′,4′,6′-tri-tert-butylphenyl)phosphacyclodeca-3,8-diyne sulfide (9c) are reported.

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Bibliographic Details
Main Authors: Popp, Ralf (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 24 August 2000
In: Tetrahedron letters
Year: 2000, Volume: 41, Issue: 21, Pages: 4075-4078
ISSN:1873-3581
DOI:10.1016/S0040-4039(00)00551-7
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/S0040-4039(00)00551-7
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0040403900005517
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Author Notes:Ralf Popp, Rolf Gleiter and Frank Rominger
Description
Summary:The first synthesis of medium-sized cyclic 1-arylphosphadiynes is reported. Details of the molecular structure of 1-phenylphosphacyclododeca-3,10-diyne sulfide (9b) and 1-(2′,4′,6′-tri-tert-butylphenyl)phosphacyclodeca-3,8-diyne sulfide (9c) are reported.
Item Description:Gesehen am 13.11.2020
Physical Description:Online Resource
ISSN:1873-3581
DOI:10.1016/S0040-4039(00)00551-7