Synthesis of a superphane dimer: a metallocenophane with four metal centers
The first dimeric bis(η5-cyclopentadienyl-η4-cyclobutadienyl–cobalt)superphane has been synthesized. It represents a metallocenophane with four cobalt centers which are electrochemically active. Cyclic voltammetric (CV) studies revealed two reversible oxidation potentials at 500 and 870 mV and two i...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
30 July 2001
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| In: |
Tetrahedron letters
Year: 2001, Volume: 42, Issue: 34, Pages: 5871-5873 |
| ISSN: | 1873-3581 |
| DOI: | 10.1016/S0040-4039(01)01142-X |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/S0040-4039(01)01142-X Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S004040390101142X 
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| Author Notes: | Rolf Roers, Jasmin Hofmann, Joerg Classen and Rolf Gleiter |
| Summary: | The first dimeric bis(η5-cyclopentadienyl-η4-cyclobutadienyl–cobalt)superphane has been synthesized. It represents a metallocenophane with four cobalt centers which are electrochemically active. Cyclic voltammetric (CV) studies revealed two reversible oxidation potentials at 500 and 870 mV and two irreversible peaks at 1050 and 1280 mV, respectively. |
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| Item Description: | Gesehen am 13.11.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1873-3581 |
| DOI: | 10.1016/S0040-4039(01)01142-X |