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Selective even-numbered bromination of triptycene tris(thiadiazoles)

An unusual even-numbered bromination of triptycene tristhiadiazole is described, giving selectively dibromo-, tetrabromo-, and hexabromotriptycenes with two bromines each at the same phenyl ring. The new compounds can be used as precursors for extended π-conjugated systems and polymers.

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Bibliographic Details
Main Authors: Kohl, Bernd (Author) , Over, Lena Charlotte (Author) , Lohr, Thorsten (Author) , Vasylyeva, Mariya (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: October 21, 2014
In: Organic letters
Year: 2014, Volume: 16, Issue: 21, Pages: 5596-5599
ISSN:1523-7052
DOI:10.1021/ol502639x
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol502639x
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Author Notes:Bernd Kohl, Lena Charlotte Over, Thorsten Lohr, Mariya Vasylyeva, Frank Rominger, and Michael Mastalerz
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Summary:An unusual even-numbered bromination of triptycene tristhiadiazole is described, giving selectively dibromo-, tetrabromo-, and hexabromotriptycenes with two bromines each at the same phenyl ring. The new compounds can be used as precursors for extended π-conjugated systems and polymers.
Item Description:Gesehen am 01.12.2020
Physical Description:Online Resource
ISSN:1523-7052
DOI:10.1021/ol502639x

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