2,6-Bis(5,6-dipropyl-1,2,4-triazin-3-yl)-pyridine: structures of An(III) and Ln(III) 1:3 complexes and selectivity
In continuation of previous studies, 1:3 complexes between Sm(III), Dy(III), Ho(III) or Tm(III) and 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)-pyridine (n-Pr-BTP) are prepared and their coordination structure in solution characterised by means of extended X-ray absorption fine structure (EXAFS). In ad...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2013
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| In: |
Inorganic chemistry communications
Year: 2012, Volume: 29, Pages: 172-174 |
| DOI: | 10.1016/j.inoche.2012.11.032 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.inoche.2012.11.032 Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S1387700312005643 
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| Author Notes: | Nidhu L. Banik, Melissa A. Denecke, Andreas Geist, Giuseppe Modolo, Petra J. Panak, Jörg Rothe |
| Summary: | In continuation of previous studies, 1:3 complexes between Sm(III), Dy(III), Ho(III) or Tm(III) and 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)-pyridine (n-Pr-BTP) are prepared and their coordination structure in solution characterised by means of extended X-ray absorption fine structure (EXAFS). In addition, distribution ratios DM(III) for the extraction of Np(III), Cf(III) and Pm(III) are determined and compared to those for Pu(III), Am(III), Cm(III) and the other Ln(III). |
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| Item Description: | Gesehen am 02.12.2020 First published: 22 December 2012 |
| Physical Description: | Online Resource |
| DOI: | 10.1016/j.inoche.2012.11.032 |