2,6-Bis(5,6-dipropyl-1,2,4-triazin-3-yl)-pyridine: structures of An(III) and Ln(III) 1:3 complexes and selectivity

In continuation of previous studies, 1:3 complexes between Sm(III), Dy(III), Ho(III) or Tm(III) and 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)-pyridine (n-Pr-BTP) are prepared and their coordination structure in solution characterised by means of extended X-ray absorption fine structure (EXAFS). In ad...

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Hauptverfasser: Banik, Nidhu Lal (VerfasserIn) , Denecke, Melissa Anne (VerfasserIn) , Geist, Andreas (VerfasserIn) , Modolo, Giuseppe (VerfasserIn) , Panak, Petra (VerfasserIn) , Rothe, Jörg (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2013
In: Inorganic chemistry communications
Year: 2012, Jahrgang: 29, Pages: 172-174
DOI:10.1016/j.inoche.2012.11.032
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.inoche.2012.11.032
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S1387700312005643
Volltext
Verfasserangaben:Nidhu L. Banik, Melissa A. Denecke, Andreas Geist, Giuseppe Modolo, Petra J. Panak, Jörg Rothe
Beschreibung
Zusammenfassung:In continuation of previous studies, 1:3 complexes between Sm(III), Dy(III), Ho(III) or Tm(III) and 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)-pyridine (n-Pr-BTP) are prepared and their coordination structure in solution characterised by means of extended X-ray absorption fine structure (EXAFS). In addition, distribution ratios DM(III) for the extraction of Np(III), Cf(III) and Pm(III) are determined and compared to those for Pu(III), Am(III), Cm(III) and the other Ln(III).
Beschreibung:Gesehen am 02.12.2020
First published: 22 December 2012
Beschreibung:Online Resource
DOI:10.1016/j.inoche.2012.11.032