Dielectric function and degradation process of poly(triarylamine) (PTAA)
We investigated the optical properties and the degradation process of the organic p-type semiconductor poly(triarylamine) (PTAA) in the mid infrared region. The dielectric function of PTAA was determined in the spectral region of 700 up to 6000cm−1 by modeling ellipsometric measurements. Due to degr...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
4 September 2014
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| In: |
Organic electronics
Year: 2014, Volume: 15, Issue: 11, Pages: 2959-2963 |
| DOI: | 10.1016/j.orgel.2014.08.037 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.orgel.2014.08.037 Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S1566119914003656 |
| Author Notes: | Michael Sendner, Jens Trollmann, Annemarie Pucci |
| Summary: | We investigated the optical properties and the degradation process of the organic p-type semiconductor poly(triarylamine) (PTAA) in the mid infrared region. The dielectric function of PTAA was determined in the spectral region of 700 up to 6000cm−1 by modeling ellipsometric measurements. Due to degradation at 65°C, PTAA thin films developed carbonyl and hydroxyl features in the infrared spectra. Degradation under 85%RH additionally led to absorption signals of water. A degradation of the bare gold substrates was also observed. For bare gold films, morphology changed upon degradation and adsorption of hydrocarbons from the ambience took place. |
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| Item Description: | Gesehen am 07.12.2020 |
| Physical Description: | Online Resource |
| DOI: | 10.1016/j.orgel.2014.08.037 |