Dielectric function and degradation process of poly(triarylamine) (PTAA)

We investigated the optical properties and the degradation process of the organic p-type semiconductor poly(triarylamine) (PTAA) in the mid infrared region. The dielectric function of PTAA was determined in the spectral region of 700 up to 6000cm−1 by modeling ellipsometric measurements. Due to degr...

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Bibliographic Details
Main Authors: Sendner, Michael (Author) , Trollmann, Jens (Author) , Pucci, Annemarie (Author)
Format: Article (Journal)
Language:English
Published: 4 September 2014
In: Organic electronics
Year: 2014, Volume: 15, Issue: 11, Pages: 2959-2963
DOI:10.1016/j.orgel.2014.08.037
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.orgel.2014.08.037
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S1566119914003656
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Author Notes:Michael Sendner, Jens Trollmann, Annemarie Pucci
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Summary:We investigated the optical properties and the degradation process of the organic p-type semiconductor poly(triarylamine) (PTAA) in the mid infrared region. The dielectric function of PTAA was determined in the spectral region of 700 up to 6000cm−1 by modeling ellipsometric measurements. Due to degradation at 65°C, PTAA thin films developed carbonyl and hydroxyl features in the infrared spectra. Degradation under 85%RH additionally led to absorption signals of water. A degradation of the bare gold substrates was also observed. For bare gold films, morphology changed upon degradation and adsorption of hydrocarbons from the ambience took place.
Item Description:Gesehen am 07.12.2020
Physical Description:Online Resource
DOI:10.1016/j.orgel.2014.08.037