Phosphorus post-functionalization of diphosphahexaarenes
Diphosphahexaarenes are highly stable π-extended frameworks containing two six-membered phosphorus heterocycles that have emerged recently. Herein, we present a detailed investigation on the post-functionalization reactions of their phosphorus centers with special emphasis on the selectivity of the...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 July 219
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| In: |
Chemistry - a European journal
Year: 2019, Volume: 25, Issue: 57, Pages: 13146-13151 |
| ISSN: | 1521-3765 |
| DOI: | https://doi.org/10.1002/chem.201901837 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/chem.201901837 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201901837 
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| Author Notes: | Philip Hindenberg, Frank Rominger, and Carlos Romero‐Nieto |
| Summary: | Diphosphahexaarenes are highly stable π-extended frameworks containing two six-membered phosphorus heterocycles that have emerged recently. Herein, we present a detailed investigation on the post-functionalization reactions of their phosphorus centers with special emphasis on the selectivity of the processes and the impact of the phosphorus functionalizations into the physicochemical properties. These studies reveal that indeed the phosphorus atoms of the diphosphahexaarenes are readily available to be functionalized with quaternizing and oxidizing agents as well as borane groups without compromising the stability of the system. In addition, the optoelectronic properties of the diphosphahexaarenes are impacted by the phosphorus post-modifications. |
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| Item Description: | Gesehen am 18.01.2021 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | https://doi.org/10.1002/chem.201901837 |