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Gold meets rhodium: tandem one-pot synthesis of β-disubstituted ketones via Meyer-Schuster rearrangement and asymmetric 1,4-addition

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An asymmetric one-pot tandem Au/Rh-catalyzed synthesis of highly enantioenriched β-disubstituted ketones starting from racemic propargyl alcohols is disclosed. The compatibility of the two metal complexes (Au/Rh) and their orthogonal ligand systems (NHC/diene) in this bimetallic catalytic system is...

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Bibliographic Details
Main Authors: Hansmann, Max M. (Author) , Hashmi, A. Stephen K. (Author) , Lautens, Mark (Author)
Format: Article (Journal)
Language:English
Published: 06/18/2013
In: Organic letters
Year: 2013, Volume: 15, Issue: 13, Pages: 3226-3229
ISSN:1523-7052
DOI:10.1021/ol4011739
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol4011739
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Author Notes:Max M. Hansmann, A. Stephen K. Hashmi, and Mark Lautens
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Summary:An asymmetric one-pot tandem Au/Rh-catalyzed synthesis of highly enantioenriched β-disubstituted ketones starting from racemic propargyl alcohols is disclosed. The compatibility of the two metal complexes (Au/Rh) and their orthogonal ligand systems (NHC/diene) in this bimetallic catalytic system is investigated.
Item Description:Gesehen am 25.02.2021
Physical Description:Online Resource
ISSN:1523-7052
DOI:10.1021/ol4011739

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