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Highly active mononuclear NAC-gold(I) catalysts

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One gold is enough: Mononuclear, homogeneous gold catalysts displayed excellent catalytic activity on the order of that previously reported for gold nanoparticle catalysts and surface-bound gold complexes. In the model synthesis of spiro compounds (see picture) extremely high turnover numbers were a...

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Bibliographic Details
Main Authors: Blanco Jaimes, Maria Camila (Author) , Böhling, Constantin R. N. (Author) , Serrano‐Becerra, Juan Manuel (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 20 June 2013
In: Angewandte Chemie. International edition
Year: 2013, Volume: 52, Issue: 31, Pages: 7963-7966
ISSN:1521-3773
DOI:https://doi.org/10.1002/anie.201210351
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/anie.201210351
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201210351
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Author Notes:Maria Camila Blanco Jaimes, Constantin R.N. Böhling, Juan Manuel Serrano‐Becerra, and A. Stephen K. Hashmi
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Summary:One gold is enough: Mononuclear, homogeneous gold catalysts displayed excellent catalytic activity on the order of that previously reported for gold nanoparticle catalysts and surface-bound gold complexes. In the model synthesis of spiro compounds (see picture) extremely high turnover numbers were achieved with only 0.000001 mol % of a silsesquioxane-substituted catalyst.
Item Description:Gesehen am 24.03.2021
Physical Description:Online Resource
ISSN:1521-3773
DOI:https://doi.org/10.1002/anie.201210351

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