Cover Picture: Giant residual dipolar 13C-1H couplings in high-spin Organoiron complexes: elucidation of their structures in solution by 13C NMR spectroscopy

The paramagnetic FeII high-spin complexes which partially align in the magnetic field of the NMR spectrometer. This results in giant residual diploar couplings (RDCs), the analysis of which allows the structural refinement of the iron complexes. The approach provides an additional analytical tool fo...

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Bibliographic Details
Main Authors: Kruck, Matthias (Author) , Wadepohl, Hubert (Author) , Enders, Markus (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 17 January 2013
In: Chemistry - a European journal
Year: 2013, Volume: 19, Issue: 5, Pages: 1513-1513
ISSN:1521-3765
DOI:10.1002/chem.201390010
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201390010
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201390010
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Author Notes:Matthias Kruck, Prof. Dr. Hubert Wadepohl, Prof. Dr. Markus Enders, Prof. Dr. Lutz H. Gade
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Summary:The paramagnetic FeII high-spin complexes which partially align in the magnetic field of the NMR spectrometer. This results in giant residual diploar couplings (RDCs), the analysis of which allows the structural refinement of the iron complexes. The approach provides an additional analytical tool for the characterization of small paramagnetic complexes in solution. The study has been carried out in Heidelberg and its castle is shown in the background. For more details see the Full Paper by M. Enders, L. Gade et al. on page 1599 ff (Chem. Eur. J. 5/2013).
Item Description:The article was published online: January 10, 2013
Im Titel ist die Zahl "13" und "1" hochgestellt
Im Zusatz zum Titel ist die Zahl "13" hochgestellt
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Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201390010