Phosphonium-iodonium ylides with heteroatomic groups in the synthesis of annelated P-containing heterocycles
The preparation and chemistry of novel sulfonyl- and phosphoryl-derived λ3-iodanes are reported. These compounds with three different heteroatoms attached to a negatively charged C atom represent potentially useful reagents that combine in one molecule the synthetic advantages of a phosphonium ylide...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
October 3, 2013
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| In: |
The journal of organic chemistry
Year: 2013, Volume: 78, Issue: 23, Pages: 11691-11697 |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo401514d |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jo401514d
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| Author Notes: | Elena D. Matveeva, Tatyana A. Podrugina, Marina A. Taranova, Dmitriy S. Vinogradov, Rolf Gleiter, and Nikolay S. Zefirov |
| Summary: | The preparation and chemistry of novel sulfonyl- and phosphoryl-derived λ3-iodanes are reported. These compounds with three different heteroatoms attached to a negatively charged C atom represent potentially useful reagents that combine in one molecule the synthetic advantages of a phosphonium ylide and an iodonium salt. Specifically, they can react with a number of acetylenes, leading to hitherto unknown sulfonyl- and phosphoryl-substituted phosphinolines, phosphininothiophenes, and a novel type of annelated P-containing heterocycle—phosphininopyrazole. |
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| Item Description: | Gesehen am 29.06.2021 |
| Physical Description: | Online Resource |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo401514d |