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Gold-catalyzed highly diastereoselective aynthesis of functionalized 3,4-disubstituted butyrolactams via phosphatyloxy or carbonate double migrations

A gold-catalyzed highly diastereoselective synthesis of functionalised 3,4-disubstituted butyrolactams via phosphatyloxy or carbonate double migrations is reported, which is proposed to proceed by a tandem 1,3-phosphatyloxy or carbonate migration and a “long-range” 1,5-phosphatyloxy or carbonate mig...

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Bibliographic Details
Main Authors: Yang, Weibo (Author) , Zhang, Tuo (Author) , Hansmann, Max M. (Author) , Pflästerer, Daniel (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 12 July 2013
In: Advanced synthesis & catalysis
Year: 2013, Volume: 355, Issue: 10, Pages: 2037-2043
ISSN:1615-4169
DOI:10.1002/adsc.201300158
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201300158
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201300158
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Author Notes:Weibo Yang, Yang Yu, Tuo Zhang, Max M. Hansmann, Daniel Pflästerer, and A. Stephen K. Hashmi
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Summary:A gold-catalyzed highly diastereoselective synthesis of functionalised 3,4-disubstituted butyrolactams via phosphatyloxy or carbonate double migrations is reported, which is proposed to proceed by a tandem 1,3-phosphatyloxy or carbonate migration and a “long-range” 1,5-phosphatyloxy or carbonate migration, which overall corresponds to a formal 1,6-migration.
Item Description:Gesehen am 23.07.2021
Physical Description:Online Resource
ISSN:1615-4169
DOI:10.1002/adsc.201300158

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