Synthese und Struktur von N,N′-Diisopropylamidinat-substituierten Oligogallanen GanRnI2 (n ≤ 4) = Syntheses and structures of N,N′-diisopropylamidinate-substituted oligogallanes GanRnI2 (n ≤ 4)
The reaction of galliumsubiodide with lithiumamidinates Li(NR)2CR′ results in formation of oligogallanes Gan(NR)2CR′nI2. The chains are built from up to four gallium atoms depending on the steric demand of the amidinates. All new compounds were characterized by NMR and crystal structure analysis and...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
15 July 2013
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| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2013, Volume: 639, Issue: 12/13, Pages: 2224-2232 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.201300127 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.201300127 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.201300127 
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| Author Notes: | Thomas Zessin, Julian Anton, und Gerald Linti |
| Summary: | The reaction of galliumsubiodide with lithiumamidinates Li(NR)2CR′ results in formation of oligogallanes Gan(NR)2CR′nI2. The chains are built from up to four gallium atoms depending on the steric demand of the amidinates. All new compounds were characterized by NMR and crystal structure analysis and DFT calculations were used to evaluate structural variations. |
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| Item Description: | Im Titel sind im Ausdruck "GanRnI2" der Buchstabe n und die Zahl 2 tiefgestellt Gesehen am 28.07.2021 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.201300127 |