1,2-migrations onto gold carbene centers
Gold carbenes are highly active intermediates in homogeneous gold catalysis, enabling a large array of transformations such as C-H/X-H insertions, cyclopropanations, and 1,2-migrations. Unlike C-H/X-H insertions and cyclopropanations, 1,2-migrations onto gold carbene centers seem to be attracting le...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2021
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| In: |
Chemical reviews
Year: 2021, Volume: 121, Issue: 14, Pages: 8948-8978 |
| ISSN: | 1520-6890 |
| DOI: | 10.1021/acs.chemrev.0c00811 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.chemrev.0c00811
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| Author Notes: | Tao Wang and A. Stephen K. Hashmi |
| Summary: | Gold carbenes are highly active intermediates in homogeneous gold catalysis, enabling a large array of transformations such as C-H/X-H insertions, cyclopropanations, and 1,2-migrations. Unlike C-H/X-H insertions and cyclopropanations, 1,2-migrations onto gold carbene centers seem to be attracting less attention. There has been no comprehensive review focusing on this topic, even though this chemistry has become a powerful tool for the rapid and simple construction of molecular complexity. This review provides comprehensive and critical information on the 1,2-migrations onto gold carbene centers, drawing a preliminary conclusion on the migratory aptitude of various groups. The review is divided into several parts according to the kind of carbene precursors. |
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| Item Description: | Published: October 7, 2020 Gesehen am 30.09.2021 |
| Physical Description: | Online Resource |
| ISSN: | 1520-6890 |
| DOI: | 10.1021/acs.chemrev.0c00811 |