Facile synthetic approach to a large variety of soluble diarenoperylenes
Fused, extended π-systems such as larger acenes and heteroacenes are interesting compounds for organic thin-film transistors (TFTs). The larger the number of linearly cata-fused rings, the lower the stability of the acenes. By peri-fusion of additional rings, the stabilities can significantly be inc...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
18 July 2016
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| In: |
Chemistry - a European journal
Year: 2016, Volume: 22, Issue: 42, Pages: 14840-14845 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201603336 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201603336 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201603336 
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| Author Notes: | Gang Zhang, Frank Rominger, Ute Zschieschang, Hagen Klauk, and Michael Mastalerz |
| Summary: | Fused, extended π-systems such as larger acenes and heteroacenes are interesting compounds for organic thin-film transistors (TFTs). The larger the number of linearly cata-fused rings, the lower the stability of the acenes. By peri-fusion of additional rings, the stabilities can significantly be increased. Here we present a facile approach to use a diborylated dihydroanthracene as precursor to get diareno-fused perylenes in just two steps in high yields. The compounds show pronounced packing in the crystalline states by π-stacking. Promising candidates have been used to fabricate p-channel TFTs by vacuum sublimation showing field-effect mobilities up to 0.12 cm2 V−1 s−1. |
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| Item Description: | Gesehen am 04.10.2021 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201603336 |