Reaction pathways and redox states in α-selective cobalt-catalyzed hydroborations of alkynes

Cobalt(II) alkyl complexes supported by a monoanionic NNN pincer ligand are pre-catalysts for the regioselective hydroboration of terminal alkynes, yielding the Markovnikov products with α:β-(E) ratios of up to 97:3. A cobalt(II) hydride and a cobalt(II) vinyl complex appear to determine the main re...

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Bibliographic Details
Main Authors:	Blasius, Clemens K. (Author) , Vasilenko, Vladislav (Author) , Matveeva, Regina (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format:	Article (Journal)
Language:	English
Published:	2020
In:	Angewandte Chemie. International edition Year: 2020, Volume: 59, Issue: 51, Pages: 23010-23014
ISSN:	1521-3773
DOI:	10.1002/anie.202009625
Online Access:	Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202009625 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202009625
Author Notes:	Clemens K. Blasius, Vladislav Vasilenko, Regina Matveeva, Hubert Wadepohl, Lutz H. Gade

Reaction pathways and redox states in α-selective cobalt-catalyzed hydroborations of alkynes by Blasius, Clemens K. (Author) , Vasilenko, Vladislav (Author) , Matveeva, Regina (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author) ,

in: Angewandte Chemie, 59 (2020), 51, Seite 23210-23214

Article (Journal) Online Resource

Reaction pathways and redox states in α-selective cobalt-catalyzed hydroborations of alkynes

Reaction pathways and redox states in α-selective cobalt-catalyzed hydroborations of alkynes by Blasius, Clemens K. (Author) , Vasilenko, Vladislav (Author) , Matveeva, Regina (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author) ,

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