Reaction pathways and redox states in α-selective cobalt-catalyzed hydroborations of alkynes
Cobalt(II) alkyl complexes supported by a monoanionic NNN pincer ligand are pre-catalysts for the regioselective hydroboration of terminal alkynes, yielding the Markovnikov products with α:β-(E) ratios of up to 97:3. A cobalt(II) hydride and a cobalt(II) vinyl complex appear to determine the main re...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2020
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| In: |
Angewandte Chemie. International edition
Year: 2020, Jahrgang: 59, Heft: 51, Pages: 23010-23014 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202009625 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202009625 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202009625 
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| Verfasserangaben: | Clemens K. Blasius, Vladislav Vasilenko, Regina Matveeva, Hubert Wadepohl, Lutz H. Gade |
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