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Selective alkylation of amines with alcohols by Cp*-iridium(III) half-sandwich complexes

[Cp*Ir(Pro)Cl] (Pro = prolinato) was identified among a series of Cp*-iridium half-sandwich complexes as a highly reactive and selective catalyst for the alkylation of amines with alcohols. It is active under mild conditions in either toluene or water without the need for base or other additives, to...

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Bibliographic Details
Main Authors: Wetzel, Alexander (Author) , Wöckel, Simone (Author) , Schelwies, Mathias (Author) , Brinks, Marion K. (Author) , Rominger, Frank (Author) , Hofmann, Peter (Author) , Limbach, Michael (Author)
Format: Article (Journal)
Language:English
Published: 01/03/2013
In: Organic letters
Year: 2013, Volume: 15, Issue: 2, Pages: 266-269
ISSN:1523-7052
DOI:10.1021/ol303075h
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol303075h
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Author Notes:Alexander Wetzel, Simone Wöckel, Mathias Schelwies, Marion K. Brinks, Frank Rominger, Peter Hofmann, and Michael Limbach
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Summary:[Cp*Ir(Pro)Cl] (Pro = prolinato) was identified among a series of Cp*-iridium half-sandwich complexes as a highly reactive and selective catalyst for the alkylation of amines with alcohols. It is active under mild conditions in either toluene or water without the need for base or other additives, tolerates a wide range of alcohols and amines, and gives secondary amines in good to excellent isolated yields.
Item Description:Gesehen am 04.11.2021
Physical Description:Online Resource
ISSN:1523-7052
DOI:10.1021/ol303075h

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