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4,4′,5,5′-tetrakis(guanidinyl)binaphthyl - synthesis and properties of two redox-active ligands and oxidative C-C coupling to perylene derivatives

We report the synthesis and properties of the new redox-active ligands 4,4′,5,5′-tetrakis(tetramethylguanidinyl)binaphthyl and 4,4′,5,5′-tetrakis(N,N′-dimethylethyleneguanidinyl)binaphthyl. The first dinuclear zinc complexes were prepared. Oxidative C-C coupling of these compounds leads to perylene...

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Main Authors: Wiesner, Sven (Author) , Ziesak, Alexandra Sabrina (Author) , Reinmuth, Matthias (Author) , Walter, Petra (Author) , Kaifer, Elisabeth (Author) , Wadepohl, Hubert (Author) , Himmel, Hans-Jörg (Author)
Format: Article (Journal)
Language:English
Published: 2013
In: European journal of inorganic chemistry
Year: 2013, Issue: 1, Pages: 163-171
ISSN:1099-0682
DOI:10.1002/ejic.201200784
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.201200784
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201200784
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Author Notes:Sven Wiesner, Alexandra Ziesak, Matthias Reinmuth, Petra Walter, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel
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Summary:We report the synthesis and properties of the new redox-active ligands 4,4′,5,5′-tetrakis(tetramethylguanidinyl)binaphthyl and 4,4′,5,5′-tetrakis(N,N′-dimethylethyleneguanidinyl)binaphthyl. The first dinuclear zinc complexes were prepared. Oxidative C-C coupling of these compounds leads to perylene derivatives.
Item Description:Published Online: October 30, 2012
Gesehen am 08.11.2021
Physical Description:Online Resource
ISSN:1099-0682
DOI:10.1002/ejic.201200784

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