4,4′,5,5′-tetrakis(guanidinyl)binaphthyl - synthesis and properties of two redox-active ligands and oxidative C-C coupling to perylene derivatives
We report the synthesis and properties of the new redox-active ligands 4,4′,5,5′-tetrakis(tetramethylguanidinyl)binaphthyl and 4,4′,5,5′-tetrakis(N,N′-dimethylethyleneguanidinyl)binaphthyl. The first dinuclear zinc complexes were prepared. Oxidative C-C coupling of these compounds leads to perylene...
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| Main Authors: | , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
2013
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| In: |
European journal of inorganic chemistry
Year: 2013, Issue: 1, Pages: 163-171 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201200784 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.201200784 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201200784 |
| Author Notes: | Sven Wiesner, Alexandra Ziesak, Matthias Reinmuth, Petra Walter, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel |
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| 520 | |a We report the synthesis and properties of the new redox-active ligands 4,4′,5,5′-tetrakis(tetramethylguanidinyl)binaphthyl and 4,4′,5,5′-tetrakis(N,N′-dimethylethyleneguanidinyl)binaphthyl. The first dinuclear zinc complexes were prepared. Oxidative C-C coupling of these compounds leads to perylene derivatives. | ||
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