TIPS-tetracene- and TIPS-pentacene-annulated poly(norbornadiene)s: synthesis and properties

The synthesis of tetracene- and pentacene-annulated norbornadienes, formed through the Diels-Alder reaction of a dehydroacene with cyclopentadiene is reported. Ring-opening metathesis polymerization (ROMP) leads to polymers that are investigated with respect to their physical, optical, and electroni...

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Hauptverfasser: Porz, Michael (VerfasserIn) , Paulus, Fabian (VerfasserIn) , Höfle, Stefan (VerfasserIn) , Lutz, Tobias (VerfasserIn) , Lemmer, Uli (VerfasserIn) , Colsmann, Alexander (VerfasserIn) , Bunz, Uwe H. F. (VerfasserIn)
Dokumenttyp: Article (Journal) Editorial
Sprache:Englisch
Veröffentlicht: September 18, 2013
In: Macromolecular rapid communications
Year: 2013, Jahrgang: 34, Heft: 20, Pages: 1611-1617
ISSN:1521-3927
DOI:10.1002/marc.201300557
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/marc.201300557
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.201300557
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Verfasserangaben:Michael Porz, Fabian Paulus, Stefan Höfle, Tobias Lutz, Uli Lemmer, Alexander Colsmann, Uwe H.F. Bunz
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Zusammenfassung:The synthesis of tetracene- and pentacene-annulated norbornadienes, formed through the Diels-Alder reaction of a dehydroacene with cyclopentadiene is reported. Ring-opening metathesis polymerization (ROMP) leads to polymers that are investigated with respect to their physical, optical, and electronic properties by gel permeation chromatography (GPC), UV-vis spectroscopy, and cyclic voltammetry. The pentacene-containing polymer P1 is successfully integrated into an organic field-effect transistor (OFET); the tetracene-containing polymer P2 is integrated into an organic light-emitting diode (OLED).
Beschreibung:Gesehen am 07.12.2021
Beschreibung:Online Resource
ISSN:1521-3927
DOI:10.1002/marc.201300557