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Pd/C-mediated depropargylation of propargyl ethers/amines in water

Propargyl ethers and amines are effectively depropargylated to the parent alcohols or amines via a C−O/C−N bond cleavage catalyzed by 10% Pd/C in water. This simple, facile, and inexpensive methodology could be utilized for the selective removal of propargyl groups from a variety of aryl ethers and...

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Bibliographic Details
Main Authors: Rambabu, Dandela (Author) , Bhavani, S. (Author) , Nalivela, Kumara Swamy (Author) , Basaveswara Rao, M. V. (Author) , Pal, Manojit (Author)
Format: Article (Journal)
Language:English
Published: 2 January 2013
In: Tetrahedron letters
Year: 2013, Volume: 54, Issue: 9, Pages: 1169-1173
ISSN:1873-3581
DOI:10.1016/j.tetlet.2012.12.093
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.tetlet.2012.12.093
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0040403912022460
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Author Notes:D. Rambabu, S. Bhavani, Nalivela Kumara Swamy, M.V. Basaveswara Rao, Manojit Pal
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Summary:Propargyl ethers and amines are effectively depropargylated to the parent alcohols or amines via a C−O/C−N bond cleavage catalyzed by 10% Pd/C in water. This simple, facile, and inexpensive methodology could be utilized for the selective removal of propargyl groups from a variety of aryl ethers and amines.
Item Description:Gesehen am 07.01.2022
Physical Description:Online Resource
ISSN:1873-3581
DOI:10.1016/j.tetlet.2012.12.093

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