Pd/C-mediated depropargylation of propargyl ethers/amines in water
Propargyl ethers and amines are effectively depropargylated to the parent alcohols or amines via a C−O/C−N bond cleavage catalyzed by 10% Pd/C in water. This simple, facile, and inexpensive methodology could be utilized for the selective removal of propargyl groups from a variety of aryl ethers and...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2 January 2013
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| In: |
Tetrahedron letters
Year: 2013, Jahrgang: 54, Heft: 9, Pages: 1169-1173 |
| ISSN: | 1873-3581 |
| DOI: | 10.1016/j.tetlet.2012.12.093 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.tetlet.2012.12.093 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0040403912022460 
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| Verfasserangaben: | D. Rambabu, S. Bhavani, Nalivela Kumara Swamy, M.V. Basaveswara Rao, Manojit Pal |
| Zusammenfassung: | Propargyl ethers and amines are effectively depropargylated to the parent alcohols or amines via a C−O/C−N bond cleavage catalyzed by 10% Pd/C in water. This simple, facile, and inexpensive methodology could be utilized for the selective removal of propargyl groups from a variety of aryl ethers and amines. |
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| Beschreibung: | Gesehen am 07.01.2022 |
| Beschreibung: | Online Resource |
| ISSN: | 1873-3581 |
| DOI: | 10.1016/j.tetlet.2012.12.093 |