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Gold(III) meets azulene: a class of [(tBuC∧N∧C)AuIII(azulenyl)] Pincer complexes

A synthetic route to new gold(III) complexes was developed. From a [(tBuC∧N∧C)AuCl] complex as a precursor, a substitution by different azulene moieties was achieved. Because of the extraordinary photophysical properties of both substituted [(C∧N∧C)Au] compounds and azulene building blocks, the fusi...

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Main Authors: Eppel, Daniel (Author) , Oberhof, Nils (Author) , Dietl, Martin C. (Author) , Cieslik, Patrick (Author) , Rudolph, Matthias (Author) , Eberle, Lukas (Author) , Krämer, Petra (Author) , Stuck, Fabian (Author) , Rominger, Frank (Author) , Dreuw, Andreas (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: November 15, 2021
In: Organometallics
Year: 2021, Volume: 40, Issue: 23, Pages: 3865-3870
ISSN:1520-6041
DOI:10.1021/acs.organomet.1c00535
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.organomet.1c00535
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Author Notes:Daniel Eppel, Nils Oberhof, Martin C. Dietl, Patrick Cieslik, Matthias Rudolph, Lukas Eberle, Petra Krämer, Fabian Stuck, Frank Rominger, Andreas Dreuw, A. Stephen K. Hashmi
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Summary:A synthetic route to new gold(III) complexes was developed. From a [(tBuC∧N∧C)AuCl] complex as a precursor, a substitution by different azulene moieties was achieved. Because of the extraordinary photophysical properties of both substituted [(C∧N∧C)Au] compounds and azulene building blocks, the fusion of these generated organometallic azulene/gold(III) pincer hybrids. The isolated complexes were fully characterized and investigated, including X-ray single-crystal structure analysis, the electrochemical properties, and UV-vis spectra.
Item Description:Gesehen am 20.01.2022
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/acs.organomet.1c00535

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