Gold(III) meets azulene: a class of [(tBuC∧N∧C)AuIII(azulenyl)] Pincer complexes
A synthetic route to new gold(III) complexes was developed. From a [(tBuC∧N∧C)AuCl] complex as a precursor, a substitution by different azulene moieties was achieved. Because of the extraordinary photophysical properties of both substituted [(C∧N∧C)Au] compounds and azulene building blocks, the fusi...
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| Hauptverfasser: | , , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
November 15, 2021
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| In: |
Organometallics
Year: 2021, Jahrgang: 40, Heft: 23, Pages: 3865-3870 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.1c00535 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.organomet.1c00535
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| Verfasserangaben: | Daniel Eppel, Nils Oberhof, Martin C. Dietl, Patrick Cieslik, Matthias Rudolph, Lukas Eberle, Petra Krämer, Fabian Stuck, Frank Rominger, Andreas Dreuw, A. Stephen K. Hashmi |
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| 520 | |a A synthetic route to new gold(III) complexes was developed. From a [(tBuC∧N∧C)AuCl] complex as a precursor, a substitution by different azulene moieties was achieved. Because of the extraordinary photophysical properties of both substituted [(C∧N∧C)Au] compounds and azulene building blocks, the fusion of these generated organometallic azulene/gold(III) pincer hybrids. The isolated complexes were fully characterized and investigated, including X-ray single-crystal structure analysis, the electrochemical properties, and UV-vis spectra. | ||
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