Distinguishing alternative reaction pathways by single-molecule fluorescence spectroscopy
Focus on chemical transitions: Epoxidation of a double bond in conjugation to a fluorescent dye was studied at single-molecule level. Direct observation of oxirane formation, indicated as a spectral shift from substrate to product state, revealed an alternative reaction pathway for the epoxidation r...
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| Main Authors: | , , , , , , , , , |
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| Format: | Article (Journal) Editorial |
| Language: | English |
| Published: |
April 29, 2013
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| In: |
Angewandte Chemie. International edition
Year: 2013, Volume: 52, Issue: 24, Pages: 6322-6325 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201300100 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201300100 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201300100 |
| Author Notes: | Arina Rybina, Carolin Lang, Marcel Wirtz, Kristin Grußmayer, Anton Kurz, Frank Maier, Alexander Schmitt, Oliver Trapp, Gregor Jung, and Dirk-Peter Herten |
| Summary: | Focus on chemical transitions: Epoxidation of a double bond in conjugation to a fluorescent dye was studied at single-molecule level. Direct observation of oxirane formation, indicated as a spectral shift from substrate to product state, revealed an alternative reaction pathway for the epoxidation reaction. |
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| Item Description: | Gesehen am 25.01.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201300100 |