Distinguishing alternative reaction pathways by single-molecule fluorescence spectroscopy

Focus on chemical transitions: Epoxidation of a double bond in conjugation to a fluorescent dye was studied at single-molecule level. Direct observation of oxirane formation, indicated as a spectral shift from substrate to product state, revealed an alternative reaction pathway for the epoxidation r...

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Main Authors: Rybina, Arina (Author) , Lang, Carolin (Author) , Wirtz, Marcel (Author) , Grußmayer, Kristin Stefanie (Author) , Kurz, Anton (Author) , Maier, Frank (Author) , Schmitt, Alexander (Author) , Trapp, Oliver (Author) , Jung, Gregor (Author) , Herten, Dirk-Peter (Author)
Format: Article (Journal) Editorial
Language:English
Published: April 29, 2013
In: Angewandte Chemie. International edition
Year: 2013, Volume: 52, Issue: 24, Pages: 6322-6325
ISSN:1521-3773
DOI:10.1002/anie.201300100
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201300100
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201300100
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Author Notes:Arina Rybina, Carolin Lang, Marcel Wirtz, Kristin Grußmayer, Anton Kurz, Frank Maier, Alexander Schmitt, Oliver Trapp, Gregor Jung, and Dirk-Peter Herten
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Summary:Focus on chemical transitions: Epoxidation of a double bond in conjugation to a fluorescent dye was studied at single-molecule level. Direct observation of oxirane formation, indicated as a spectral shift from substrate to product state, revealed an alternative reaction pathway for the epoxidation reaction.
Item Description:Gesehen am 25.01.2022
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.201300100