Dithieno(3,2-b:2′,3′-d)phospholes: a look back at the first decade

In this account, we describe our efforts in developing the chemistry of the highly luminescent dithieno[3,2-b:2′,3′-d]phosphole system over the last ten years. We provide an overview of the synthetic possibilities and the inherent tunability of the emission properties offered by this particular hete...

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Hauptverfasser: Romero-Nieto, Carlos (VerfasserIn) , Baumgartner, Thomas (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 11. April 2013
In: Synlett
Year: 2013, Jahrgang: 24, Heft: 8, Pages: 920-937
ISSN:1437-2096
DOI:10.1055/s-0032-1317804
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1055/s-0032-1317804
Verlag, lizenzpflichtig, Volltext: http://www.thieme-connect.de/DOI/DOI?10.1055/s-0032-1317804
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Verfasserangaben:Carlos Romero-Nieto, Thomas Baumgartner
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Zusammenfassung:In this account, we describe our efforts in developing the chemistry of the highly luminescent dithieno[3,2-b:2′,3′-d]phosphole system over the last ten years. We provide an overview of the synthetic possibilities and the inherent tunability of the emission properties offered by this particular heterole. 1 Introduction 2 Synthesis and Properties of Dithieno[3,2-b:2′,3′-d]phospholes 3 Functionalization of Dithieno[3,2-b:2′,3′-d]phospholes 3.1 Phosphorus Functionalization 3.2 Functionalization at the 2- and 6-Positions 3.2.1 Symmetric Functionalization 3.2.2 Asymmetric Functionalization 3.3 Incorporation of Fused Rings onto the Main Scaffold 4 Photophysical Properties 5 Conclusions
Beschreibung:Gesehen am 03.02.2022
Beschreibung:Online Resource
ISSN:1437-2096
DOI:10.1055/s-0032-1317804