Synthesis of large (2+3) salicylimine cages with embedded metal-salphen units
Metal salphen containing complexes have found a broad variety of applications in catalysis as well as material science. Most of these materials are either mono-nuclear complexes or polymeric network materials. Discrete macromolecular polynuclear salphens are still rare and mostly two-dimensional str...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 11, 2022
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| In: |
European journal of inorganic chemistry
Year: 2022, Issue: 1, Pages: 1-8 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.202100864 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ejic.202100864 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.202100864 
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| Author Notes: | Fabian Uhrmacher, Sven M. Elbert, Frank Rominger, and Michael Mastalerz |
| Summary: | Metal salphen containing complexes have found a broad variety of applications in catalysis as well as material science. Most of these materials are either mono-nuclear complexes or polymeric network materials. Discrete macromolecular polynuclear salphens are still rare and mostly two-dimensional structures. Here we present three-dimensional trinuclear Ni(II)- and Pt(II)-cage compounds with a covalently bound [2+3] salicylimine cage backbone. The solubility of the cages allowed their investigation by spectroscopic methods. Furthermore, the Pt(II) derivative was investigated by single crystal X-ray structure analysis revealing that the presented cage compounds possess the largest intrinsic void of metal salphen cages reported till date. |
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| Item Description: | Online veröffentlicht: 28. Oktober 2021 Im Titel steht der Ausdruck "2+3" in eckiger Klammer Gesehen am 09.02.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.202100864 |