[Ge12{FeCp(CO)2} 8 {FeCp(CO)}2]: a Ge12 core resembles the arrangement of the high-pressure modification Germanium (II)
Similar yet different: The reaction of a GeBr solution with K[FeCp(CO)2] (Cp=η-C5H5) gives [Ge12FeCp(CO)28FeCp(CO)2] (1), whose oblong, highly cross-linked cluster core reveals a cut-out of the high-pressure solid-state structure of germanium (II) (see scheme). Mass spectrometric investigations on t...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 3, 2013
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| In: |
Angewandte Chemie. International edition
Year: 2013, Volume: 52, Issue: 6, Pages: 1834-1838 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201207224 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201207224 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201207224 
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| Author Notes: | Christian Schenk, Florian Henke, and Andreas Schnepf |
| Summary: | Similar yet different: The reaction of a GeBr solution with K[FeCp(CO)2] (Cp=η-C5H5) gives [Ge12FeCp(CO)28FeCp(CO)2] (1), whose oblong, highly cross-linked cluster core reveals a cut-out of the high-pressure solid-state structure of germanium (II) (see scheme). Mass spectrometric investigations on the gas-phase species [Ge6FeCp(CO)26FeCp(CO)]− (2) and theoretical calculations on 1 and 2 illuminate the formation of the metalloid cluster 1. |
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| Item Description: | Im Titel sind "12", "8" und "2" jeweils tiefgestellt Der gesamte Haupttitel steht in eckiger Klammer Gesehen am 16.02.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201207224 |