Thermodynamic investigation of the (LiF+NaF+CaF2+LaF3) system
In this work a thermodynamic assessment of the (LiF+NaF+CaF2+LaF3) system is reported. For the thermodynamic modeling of the liquid phase, the classical polynomial model, and the modified quasi-chemical model were used in parallel and compared. The extrapolation to higher order systems was done acco...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
9 May 2011
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| In: |
The journal of chemical thermodynamics
Year: 2011, Volume: 43, Issue: 10, Pages: 1515-1524 |
| ISSN: | 1096-3626 |
| DOI: | 10.1016/j.jct.2011.05.002 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jct.2011.05.002 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0021961411001480 
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| Author Notes: | M. Beilmann, O. Beneš, R.J.M. Konings, Th. Fanghänel |
| Summary: | In this work a thermodynamic assessment of the (LiF+NaF+CaF2+LaF3) system is reported. For the thermodynamic modeling of the liquid phase, the classical polynomial model, and the modified quasi-chemical model were used in parallel and compared. The extrapolation to higher order systems was done according to the Toop mathematical formalism. Furthermore, differential-scanning calorimetry data of the ternary (LiF+CaF2+LaF3), (NaF+CaF2+LaF3), and the quaternary (LiF+NaF+CaF2+LaF3) mixtures are presented. Good agreement between the experimental data and the thermodynamic assessment was obtained. |
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| Item Description: | Gesehen am 16.03.2022 Im Titel sind die Zahlen 2 und 3 tiefgestellt |
| Physical Description: | Online Resource |
| ISSN: | 1096-3626 |
| DOI: | 10.1016/j.jct.2011.05.002 |