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Synthesis of heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes via the isonitrile route

A convenient one-pot approach to bridged heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes is presented. The methodology exploits the graduated nucleophilicities of aliphatic and aromatic amines connected via an aromatic unit. This enables a straightforward access to bridg...

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Main Authors: Dietl, Martin C. (Author) , Vethacke, Vanessa (Author) , Keshavarzi, Ali (Author) , Mulks, Florian (Author) , Rominger, Frank (Author) , Rudolph, Matthias (Author) , Mkhalid, Ibraheem A. I. (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: March 7, 2022
In: Organometallics
Year: 2022, Volume: 41, Issue: 6, Pages: 802-810
ISSN:1520-6041
DOI:10.1021/acs.organomet.2c00021
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.organomet.2c00021
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Author Notes:Martin C. Dietl, Vanessa Vethacke, Ali Keshavarzi, Florian F. Mulks, Frank Rominger, Matthias Rudolph, Ibraheem A.I. Mkhalid, and A. Stephen K. Hashmi
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Summary:A convenient one-pot approach to bridged heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes is presented. The methodology exploits the graduated nucleophilicities of aliphatic and aromatic amines connected via an aromatic unit. This enables a straightforward access to bridged complexes from easily available isonitrile metal precursors.
Item Description:Gesehen am 15.06.2022
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/acs.organomet.2c00021

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