Using pH value to control intermolecular electronic decay
pH deed: Intermolecular Coulombic decay (ICD) is an ultrafast relaxation pathway of a highly excited system. A theoretical investigation of ammonia dimers and trimers shows that the ICD efficiency is regulated by protonation or deprotonation. Varying the ICD rate by changing the environmental pH val...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
05 January 2011
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| In: |
Angewandte Chemie. International edition
Year: 2011, Volume: 50, Issue: 6, Pages: 1306-1309 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201004446 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201004446 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201004446 
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| Author Notes: | Nikolai V. Kryzhevoi and Lorenz S. Cederbaum |
| Summary: | pH deed: Intermolecular Coulombic decay (ICD) is an ultrafast relaxation pathway of a highly excited system. A theoretical investigation of ammonia dimers and trimers shows that the ICD efficiency is regulated by protonation or deprotonation. Varying the ICD rate by changing the environmental pH value provides a control over the relaxation dynamics (see scheme). |
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| Item Description: | Gesehen am 11.07.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201004446 |