Highly selective adsorption of perfluorinated greenhouse gases by porous organic cages
Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands of times more harmful to the environment than comparable amounts of carbon dioxide. To date, materials that selectively adsorb perfluorocarbons in favor of other...
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| Main Authors: | , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
03 June 2022
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| In: |
Advanced materials
Year: 2022, Volume: 34, Issue: 31, Pages: 1-12 |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202202290 |
| Online Access: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/adma.202202290 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.202202290 
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| Author Notes: | Ke Tian, Sven M. Elbert, Xin-Yue Hu, Tobias Kirschbaum, Wen-Shan Zhang, Frank Rominger, Rasmus R. Schröder, and Michael Mastalerz |
| Summary: | Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands of times more harmful to the environment than comparable amounts of carbon dioxide. To date, materials that selectively adsorb perfluorocarbons in favor of other less harmful gases have not been reported. Here, a series of porous organic cage compounds with alkyl-, fluoroalkyl-, and partially fluorinated alkyl groups is presented. Their isomorphic crystalline states allow the study of the structure-property relationship between the degree of fluorination of the alkyl chains and the gas sorption properties for PFCs and their selective uptakes in comparison to other, nonfluorinated gases. By this approach, one compound having superior selectivities of PFCs versus N2 or CO2 under ambient conditions is identified. |
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| Item Description: | Gesehen am 25.08.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202202290 |