Buchumschlag

(Acetonitrile-κN)(2-(diphenylphosphan­yl)ethanamine-κ2N,P)((1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl)iron(II) hexafluoridophosphate tetrahydrofuran monosolvate

In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6·C4H8O, the metal ion is coordinated by the η5-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl­phosphino)ethyl­amine ligand and an additional acetonitrile mol­ecule in a piano-chair conformation. The PF6− ani...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Lee, Kajin (VerfasserIn) , Rominger, Frank (VerfasserIn) , Limbach, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2011
In: Acta crystallographica. Section E, Crystallographic communications
Year: 2011, Jahrgang: 67, Heft: 8, Pages: m1135, sup1-sup2
ISSN:2056-9890
DOI:10.1107/S1600536811028832
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1107/S1600536811028832
Verlag, kostenfrei, Volltext: https://scripts.iucr.org/cgi-bin/paper?go2017
Volltext
Verfasserangaben:Kajin Lee, Frank Rominger and Michael Limbach
Beschreibung
Zusammenfassung:In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH3CN)(C14H16NP)]PF6·C4H8O, the metal ion is coordinated by the η5-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl­phosphino)ethyl­amine ligand and an additional acetonitrile mol­ecule in a piano-chair conformation. The PF6− anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).
Beschreibung:Im Titel ist 2 bei "ethanamine-κ" hochgestellt, die Ausdrücke "2-(diphenylphosphan­yl)ethanamine-κ2N,P" und "(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl" stehen jeweils in eckiger Klammer
Gesehen am 08.08.2022
Beschreibung:Online Resource
ISSN:2056-9890
DOI:10.1107/S1600536811028832

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