Gold(I)-catalyzed formation of benzo(b)furans from 3-silyloxy-1,5-enynes
Sport of kings: A new gold(I)-catalyzed transformation has been developed that occurs under mild conditions and proceeds by an expected substituent “castling” (see red and blue circles in scheme) to give efficient access to benzo[b]furans from the easy to obtain 3-silyloxy-1,5-enynes (IPr=N,N′-bis(2...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
09 May 2011
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| In: |
Angewandte Chemie. International edition
Year: 2011, Volume: 50, Issue: 25, Pages: 5762-5765 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201100989 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201100989 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201100989 
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| Author Notes: | A. Stephen K. Hashmi, Weibo Yang, and Frank Rominger |
| Summary: | Sport of kings: A new gold(I)-catalyzed transformation has been developed that occurs under mild conditions and proceeds by an expected substituent “castling” (see red and blue circles in scheme) to give efficient access to benzo[b]furans from the easy to obtain 3-silyloxy-1,5-enynes (IPr=N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, NTf2=bis(trifluoromethylsulfonylimide). |
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| Item Description: | Gesehen am 31.08.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201100989 |