Formation of exocyclic olefinic groups via stereoselective nitrosations: a new route towards pendant arm macrocyclic ligands

Nitrosation of the CuII and PdII complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy.

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Bibliographische Detailangaben
Hauptverfasser: Bernhardt, Paul V. (VerfasserIn) , Comba, Peter (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 1993
In: Journal of the Chemical Society. Chemical communications
Year: 1993, Heft: 2, Pages: 113-114
DOI:10.1039/C39930000113
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C39930000113
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/1993/c3/c39930000113
Volltext
Verfasserangaben:Paul V. Bernhardt and Peter Comba
Beschreibung
Zusammenfassung:Nitrosation of the CuII and PdII complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy.
Beschreibung:Gesehen am 02.09.2022
Beschreibung:Online Resource
DOI:10.1039/C39930000113