Formation of exocyclic olefinic groups via stereoselective nitrosations: a new route towards pendant arm macrocyclic ligands
Nitrosation of the CuII and PdII complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy.
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
1993
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| In: |
Journal of the Chemical Society. Chemical communications
Year: 1993, Heft: 2, Pages: 113-114 |
| DOI: | 10.1039/C39930000113 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C39930000113 Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/1993/c3/c39930000113 |
| Verfasserangaben: | Paul V. Bernhardt and Peter Comba |
| Zusammenfassung: | Nitrosation of the CuII and PdII complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy. |
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| Beschreibung: | Gesehen am 02.09.2022 |
| Beschreibung: | Online Resource |
| DOI: | 10.1039/C39930000113 |