Formation of exocyclic olefinic groups via stereoselective nitrosations: a new route towards pendant arm macrocyclic ligands
Nitrosation of the CuII and PdII complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy.
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
1993
|
| In: |
Journal of the Chemical Society. Chemical communications
Year: 1993, Issue: 2, Pages: 113-114 |
| DOI: | 10.1039/C39930000113 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C39930000113 Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/1993/c3/c39930000113 
|
| Author Notes: | Paul V. Bernhardt and Peter Comba |
| Summary: | Nitrosation of the CuII and PdII complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy. |
|---|---|
| Item Description: | Gesehen am 02.09.2022 |
| Physical Description: | Online Resource |
| DOI: | 10.1039/C39930000113 |