Theoretical insights into the superior activity of gold catalysts and reactions of organogold intermediates with electrophiles
Three fundamental steps of homogeneous gold catalysis, the activiation of substrates by coordination to gold, the protodeauration after the nucleophilic addition and the transmetalation to palladium in palladium-catalysed C-C bond forming reactions using organogold intermediates have been studied an...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Chapter/Article Conference Paper |
| Language: | English |
| Published: |
[2011]
|
| In: |
Gold
Year: 2011, Volume: 152, Pages: 179-184 |
| DOI: | 10.1039/C1FD00029B |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C1FD00029B Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2011/fd/c1fd00029b |
| Author Notes: | A. Stephen K. Hashmi, Markus Pernpointner and Max M. Hansmann |
| Summary: | Three fundamental steps of homogeneous gold catalysis, the activiation of substrates by coordination to gold, the protodeauration after the nucleophilic addition and the transmetalation to palladium in palladium-catalysed C-C bond forming reactions using organogold intermediates have been studied and discussed in detail. |
|---|---|
| Item Description: | Gesehen am 07.09.2022 |
| Physical Description: | Online Resource |
| DOI: | 10.1039/C1FD00029B |