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Synthesis and characterization of a doubly base-stabilized B3H6+ analogue

The answer to an old question: A doubly base-stabilized B3H6+ analogue (see structure: B green, C gray, N blue, H light gray, H on C not shown) has been synthesized and completely characterized. Quantum-chemical calculations on a simplified model confirmed the presence of closed B-B-B three-center b...

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Bibliographic Details
Main Authors: Schulenberg, Nikola (Author) , Wadepohl, Hubert (Author) , Himmel, Hans-Jörg (Author)
Format: Article (Journal)
Language:English
Published: 16 September 2011
In: Angewandte Chemie. International edition
Year: 2011, Volume: 50, Issue: 44, Pages: 10444-10447
ISSN:1521-3773
DOI:10.1002/anie.201104834
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201104834
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201104834
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Author Notes:Nikola Schulenberg, Hubert Wadepohl, and Hans-Jörg Himmel
Description
Summary:The answer to an old question: A doubly base-stabilized B3H6+ analogue (see structure: B green, C gray, N blue, H light gray, H on C not shown) has been synthesized and completely characterized. Quantum-chemical calculations on a simplified model confirmed the presence of closed B-B-B three-center bonding and σ-aromatic character.
Item Description:Die 3 und 6 im Titel sind tiefgestellt, das + ist hochgestellt
Gesehen am 27.10.2022
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.201104834

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