Synthesis and characterization of a doubly base-stabilized B3H6+ analogue
The answer to an old question: A doubly base-stabilized B3H6+ analogue (see structure: B green, C gray, N blue, H light gray, H on C not shown) has been synthesized and completely characterized. Quantum-chemical calculations on a simplified model confirmed the presence of closed B-B-B three-center b...
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Hauptverfasser: | , , |
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Dokumenttyp: | Article (Journal) |
Sprache: | Englisch |
Veröffentlicht: |
16 September 2011
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In: |
Angewandte Chemie. International edition
Year: 2011, Jahrgang: 50, Heft: 44, Pages: 10444-10447 |
ISSN: | 1521-3773 |
DOI: | 10.1002/anie.201104834 |
Online-Zugang: | lizenzpflichtig lizenzpflichtig ![]() |
Verfasserangaben: | Nikola Schulenberg, Hubert Wadepohl, and Hans-Jörg Himmel |
Zusammenfassung: | The answer to an old question: A doubly base-stabilized B3H6+ analogue (see structure: B green, C gray, N blue, H light gray, H on C not shown) has been synthesized and completely characterized. Quantum-chemical calculations on a simplified model confirmed the presence of closed B-B-B three-center bonding and σ-aromatic character. |
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Beschreibung: | Die 3 und 6 im Titel sind tiefgestellt, das + ist hochgestellt Gesehen am 27.10.2022 |
Beschreibung: | Online Resource |
ISSN: | 1521-3773 |
DOI: | 10.1002/anie.201104834 |