Redox chemistry and group 10 metal complexes of aromatic compounds with bulky bicyclic guanidino groups
The reaction between activated bicyclic tetramethylbisurea and 1,2-diaminobenzene or 1,2,4,5-tetraaminobenzene affords new aromatic compounds functionalized with bicyclic guanidino groups. Protonation and redox reactions are carried out to obtain information about the chemical properties of these ne...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
August 16, 2011
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| In: |
European journal of inorganic chemistry
Year: 2011, Issue: 27, Pages: 4220-4233 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201100479 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.201100479 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201100479 
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| Author Notes: | Ute Wild, Elisabeth Kaifer, and Hans-Jörg Himmel |
| Summary: | The reaction between activated bicyclic tetramethylbisurea and 1,2-diaminobenzene or 1,2,4,5-tetraaminobenzene affords new aromatic compounds functionalized with bicyclic guanidino groups. Protonation and redox reactions are carried out to obtain information about the chemical properties of these new guanidines. They are used as chelating ligands in mononuclear and dinuclear group 10 metal (Ni, Pd, and Pt) complexes, which could be interesting for catalytic applications. Initial experiments with a Ni complex showed a moderate activity in olefin oligomerization yielding mostly C6 hydrocarbons. |
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| Item Description: | Gesehen am 03.11.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201100479 |