An evaluation of ligand properties of neutral and anionic tris(imidazol-2-yl)phosphines

In order to study the applicability of tris(imidazol-2-yl)phosphine (PIm3) as a possible charge-variable ligand, new neutral N-butyl and N-benzyl derivatives and d0-metal complexes thereof were prepared and characterized as reference compounds for planned complexes with high valent metals. In additi...

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Bibliographic Details
Main Authors: Enders, Markus (Author) , Fritz, Olaf (Author) , Pritzkow, Hans (Author)
Format: Article (Journal)
Language:English
Published: 2004
In: Zeitschrift für anorganische und allgemeine Chemie
Year: 2004, Volume: 630, Issue: 10, Pages: 1501-1506
ISSN:1521-3749
DOI:10.1002/zaac.200400149
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200400149
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200400149
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Author Notes:Markus Enders, Olaf Fritz, Hans Pritzkow
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Summary:In order to study the applicability of tris(imidazol-2-yl)phosphine (PIm3) as a possible charge-variable ligand, new neutral N-butyl and N-benzyl derivatives and d0-metal complexes thereof were prepared and characterized as reference compounds for planned complexes with high valent metals. In addition, an anionic ligand precursor was characterized by X-Ray analysis and its reactivity towards transition metal halides assayed.
Item Description:First published: 23 August 2004
Gesehen am 18.11.2022
Physical Description:Online Resource
ISSN:1521-3749
DOI:10.1002/zaac.200400149